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With its increased demand for solders (eg, Sn-Ag-Cu), it is expected to rise in price, making it economically less attractive 4566 Tin (Sn) Tin deposited directly over copper, whether by electrolytic or electroless methods, should be avoided except for low-end/low-cost, short-field-life products Sn alloys with copper, even at room temperature, form a brittle intermetallic compound, albeit slowly It has limited solderable shelf-life at room temperature and the Sn-Cu intermetallic can inhibit soldering and may result in incomplete solder wetting or solder joints of inferior strength For tin to be used effectively, an appropriate non-porous barrier metal, such as Ni, should be deposited between the Cu and the Sn Immersion Sn can be plated only as a very thin layer since its deposition is by a self-limiting replacement reaction.

When there is no more exposed Cu on the surface of the PWB during the surface-plating operation, Sn deposition will cease Therefore, it is impossible to plate enough Sn by this method to extend the solderable shelf-life or reduce the brittleness of the solder joint..

There are essentially two halves to the binding problem: the business service has to be exposed in a consistent way, and a UI component has to know how to bind to that abstraction. In nonsoftware terms, you can think of the solution as being analogous to two pieces of VELCRO brand fasteners. One piece of Velcro, with loops, is attached over the business service, while the other piece of Velcro, with the hooks, is attached to the UI component. No matter how the business service is implemented, the UI component can always bind to it so long as it has the appropriately shaped piece of Velcro.

When fresh, tin has reasonable solderability, but also tends to oxidize quickly. There are two important phenomena that are associated with Sn platings: tin whiskers and tin pest. 45.6.6.1 Sn Whiskers. Not to be confused with corrosion dendrites, whiskers are crystallites (see Fig. 45.6) that grow from pure tin surfaces into free space whereas corrosion dendrites grow on ionic contaminated, hydrated surfaces between two charged conductors. Although whiskers have been studied since the 1940s, their root cause is yet to be fully understood.

Input is more appropriate for these pins because no buffering is provided for output loading The two-axis amplifier we will be using to run the servo and stepper motors later on in Part III of the book needs to be connected to the Propeller with six pins Pins P4 P9 have been assigned to this usage If an amplifier is not in use, these pins can also be used for any input or output application No buffers are provided on any of these lines The LCD will be connected to the Propeller initially with an 8-bit path for the data and later with a 4-bit path for the data It needs three lines for data transfer, chip select, and so on, so a total of 11 lines have been assigned to this use Only lines P12 P18 are needed if four-line LCD control is implemented.

FIGURE 45.6 Scanning electron microscope (SEM) micrograph of Sn whiskers growing from a pure Sn surface.When whiskers break, they pose danger of shorting between fine-pitch conductors. Whiskers can also grow long enough to bridge to a nearby conductor. (Courtesy of H. Hsu, Mitac Corporation, ShunDe, China).

The concern over whisker growth is related to electrical short circuits. If a tin whisker is long enough, it may break due to mechanical shock or vibration. The broken whisker may bridge two closely spaced contacts or traces on a component or PWB. Whiskers need not break to cause a short circuit, as they can grow long enough to bridge two adjacent, closely spaced conductors. In 1998, the Galaxy IV communications satellite failure was traced back to tin whiskers. Spare boards for that satellite stored on Earth clearly showed whisker growth. It is ironic that the first whisker issue occurred in 1946 on Bell telephone equipment, causing another telecommunications disruption. Theories abound with regard to tin whisker formation. There are lattice dislocation theories and grain boundary diffusion theories. But the most prevalent theory for whisker generation relates their origin to compressive stresses within the tin lattice and perhaps weak spots in the overlying natural oxide on the tin surface (see Fig. 45.7). When tin grains are compressed against each other, and particularly when there are large compressive forces against a small, near-surface grain, the small grain may start to recrystallize or extrude in the least stressful direction, outward through a weak spot in the native oxide layer. Growth will continue until the lattice energy reaches equilibrium. Tin whiskers can grow to a diameter of approximately 1 micrometer and their length can reach tens of micrometers.

FIGURE 45.7 Compressive stress within the tin lattice may cause whisker formation. The picture sequence depicts a likely mechanism for tin whisker growth and risk to printed circuit assembly: (a) A tin lattice with small, near-surface grain between two large grains. (b) Compressive stresses cause recrystallization of grain. A thin spot in the oxide layer allows rudimentary whiskers to penetrate the surface. (c) The whisker continues to grow. (d) The whisker continues to grow. (e) The whisker breaks due to mechanical shock or vibration. Whisker fragment poses a shorting risk to the PCA.