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In some applications, solder joints will fall apart if the service temperature is high and the low melting point Sn-Bi-Pb alloy is formed This becomes all the more critical with lowvolume Sn-Bi solder joints The Pb can come from solder predeposited on component leads, Sn-Pb hot-air solder leveled pads, or both Bismuth expands upon freezing, whereas tin contracts A phenomenon called fillet lifting has been reported5, 6 (see Fig 452) It is mostly associated with bismuth ternary alloys such as Sn-Cu-Bi and Sn-Ag-Bi used in plated through-hole (PTH) wave soldering, but has also been observed with Sn-Bi system..

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GS1 - 128 - Wikipedia
GS1 - 128 is an application standard of the GS1 implementation using the Code 128 barcode ... integer divided by 10 y . For example, a net weight of 22.7 kg could be coded as 3101 000227, 3102 002270, 3103 022700, or 3104 227000.

FIGURE 45.2 The expansion upon solidification in a bismuth-containing solder alloy can cause solder fillets to fracture and lift from the plated through-hole annular pads (right). Compare this to the schematic on the left, which is indicative of a conventional tin-lead solder joint.

In general, the 40 pins on the Propeller will be given the assignments outlined in Table 4-1. If this scheme is followed, some items can be left attached at all times and others that must be relocated have to be moved only occasionally. The information in this table forewarns you about what pins might be needed for our experiments so that you can assign the pins you want to use accordingly. In this table, I = input and O = output for the data flow directions.

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As the board cools, it contracts at a different rate than the solder, and the fillets may lift, especially if cooled slowly or contaminated with Pb. Rapid cooling (~3 C/sec.) has been advised but may not completely eliminate this phenomenon. Care must be taken not to exceed the component manufacturer s specified heating and cooling ramp rate. Too high a cooling rate may result in component cracking or degraded component reliability. Fillet lifting may also result in lifted PTH annular ring (bonding pad) if solder-joint strength is high and bond strength of the ring to the board is low.

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Some Bi alloys have too low a melting point for many applications Despite its excellent tensile strength and thermal cycling endurance (better than Sn-Pb), Sn-Bi eutectic (mp, 138 C) would not be practical for use in most automotive applications or even for high-end computer assembly, where the service temperature may approach the melting point of this alloy Bi also oxidizes rapidly, making Bi alloys difficult to maintain during wave soldering due to copious oxide (dross) production Bismuth soldering alloys are noted for their brittleness7,8; nonetheless, several bismuth solders are used commercially, the most popular alloys containing Bi as a minor constituent (in the 2 to 14 percent range) Aside from bismuth alloys inappropriateness for high-temperature applications and Pb contamination, safety is an issue According to C White and G Evans,9 safety is particularly a concern when using alloys with high concentrations of bismuth.

Cadmium (Cd), a poisonous metal, is a commonly associated bismuth contaminant Care is recommended in handling of this solder, and special venting requirements may also be mandated for its use On the other hand, the RoHS legislation has reinforced prior EU restrictions on cadmium, limiting it as a constituent or contaminant to less than 100 ppm by weight Bismuth and indium alloys are useful for step soldering, which refers to the use of two different solder alloys with two different melting temperatures used on the same circuit boardThe higher temperature alloy (eg, Sn-3%Ag-05%Cu, melting onset, 217 C) is used to solder surface-mount components and an alloy of lower melting temperature (eg, 58%Bi:42%Sn, mp, 138 C) is used for wave-soldered components.

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The temperature experienced at wave solder will not cause the Sn-Ag-Cu to reflow, thus preserving the integrity of surface-mount technology (SMT) solder joints In the case of repair or replacement of components, the use of low melting temperature solder will have no adverse thermal effect on adjacent or reverse-side solder joints In fact, use of low melting point solder reduces the possibility of pad delamination or through-hole barrel cracking; failure mechanisms associated with localized overheating, especially at repair 45513 Sn-Ag-Cu As previously stated, the Sn-Ag-Cu (SAC) family is receiving the most attention worldwide Its tensile strength is superior to that of Sn-Pb, but its shear strength is worse It is easily fluxed and moderate in melting temperature roughly 35 C higher than eutectic Sn-Pb solder.

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