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1. To act as chemistry that reduces oxides on a wettable surface. 2. To provide the correct interfacial energy potential between the flux/solder interface and the solder substrate interface. 3. To prevent oxidation from forming during the soldering process and to a lesser extent in the case of liquid fluxes they may protect the surface on the PCB from the extreme temperatures. It may also act as a heat transfer medium. Fluxes are necessary for soldering. While flux-free soldering is possible, in the presence of a reducing gas atmosphere, it is very uncommon. When attempting to check for solderability characteristics without the use of a flux, at best the solder will stick to the sample but will not wet the surface to form a true metallurgical bond.At the other extreme end of the scale are people using fluxes so strong that nothing will ever fail a solderability test. These fluxes do not represent anything used in the assembly industry.A great example of this is the use of the Hot Air Solder Level (HASL) flux for outgoing solderability testing. This type of flux typically uses 5 percent HCl or 5 percent HBr as the active ingredient which, when applied to a surface finish, will reduce any oxide layer present and reactivate any potentially passivated nickel layer and thus always produce a pass result. This is not what is supposed to be used and it does not provide any information pertaining to the actual solderability of the sample being tested because it passes all the time. 42.2.3.2 Fluxes and Evaluation of Solderability. There has been a fundamental change in how solderability is evaluated. The need to demonstrate a year of shelf life has been

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replaced with a test for how robust a deposit or plating is The more robust the deposit, the greater the potential shelf life and the ability to survive the complicated higher temperature exposures found in Pb-free assembly When making the choice in terms of solderability testing, it is important that the chosen flux is active enough to overcome finger oils and light surface oxidation and to promote wettingAt the same time, it should not be capable of reducing heavy oxides or wetting to exposed and oxidized intermetallic compounds For many years the use of the R flux for solderability testing was the norm, and it was referenced in that venerable specification MIL STD 202, method 208 The weight consists of 25 percent colophony and 75 percent alcohol The activation level is approximately 0.

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05 percent as measured by chloride content, since this is not very active and being a naturally occurring substance there is variation year to year and location to location The JSTD-002/003 committees working with NIST, NEMI, and Industry undertook a study to look into the use of this flux Using an R type flux for solderability testing produced excessive noise in the data, which was generated from the flux alone The inability of the flux to deal with simple soils, such as a finger print for example, could produce a false negative result The outcome of the study was a recommendation to add a known quantity of an active ingredient, low enough to not produce false positives but strong enough to deal with normal sample contamination not related to the plating or surface preparation of the sample.

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Testing of OSP, ENIG, and Palladium surface finishes with an R flux inevitably produced failures that were never seen in production These surface finishes, particularly ENIG and OSP, are in common use and a suitable flux needed to be created to test them The added ingredient was diethylammonium hydrochloride and the flux specified for solderability testing became known as a standard activated rosin flux (type ROL1 per J-STD-004) This flux has been shown to be excellent in differentiating solderability issues from finger oils and sample issues It is sold under many names The list of current suppliers can be found in the appendix of both J-STD-002 and 003 42233 Lead-Free Solderability and Fluxes For lead-free solderability testing, a further extensive study was undertaken by the J-STD-002/003 committees again The outcome of the testing was to recommend and specify the use of a more active flux.

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The activation level has been increased to 05 percent as measured by chloride content This flux and the increase in test temperature are specified in the J-STD-002C and 003B 42234 Wetting and Solderability Soldering is governed by the laws of physics In soldering, three phases are present: 1 The solid phase (parts to be soldered) 2 The liquid phase (molten alloy) 3 The vapor phase; flux evaporation (atmospheric air in the majority, could be nitrogen) The molecular interactions of these three phases taken in pairs are surface tensions (see Figs 421 and 422)..

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