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ENIG the immersion gold deposit is porous by definition. It does offer very good protection to the underlying nickel, but over time the porosity of the deposit results in the passivation of the nickel surface and as the soldering is done to this layer and not to the gold, the wetting forces are reduced. (See Fig. 42.11) This process should take years to occur. Normal storage of the boards will not impact the initial wetting time, as the dissolution rate of the gold is not impacted it dissolves at 153 microinches/second at 235 C. An example of the power of the wetting balance is the ability to detect excessive rinsing post nickel deposition: it will passivate the surface and produce slow wetting times similar to old parts. Depending on the flux activation levels used, the degree of nickel passivation can produce a total non-wet condition to an excellent wetting result. After 842 days of unprotected storage, the nickel deposit continues to wet under 0.5 seconds, but again the exterior metal immersion gold is porous by definition. So, while doing an excellent job at protecting the underlying basis nickel from passivation, time eventually takes its toll.

Keeping track of the encoder counts and at the same time managing the motor is not trivial by a long shot. A considerable amount of code has to be processed, and it has to be done constantly. No encoder counts can be dropped. On the other hand, if

0 0 3 6 0.38 0.75 1.13 1.5 1.88 2.25 2.63 3.38 3.75 4.13 4.5 4.88 5.25 5.63 6.38 6.75 7.13 7.5 7.88 8.25 8.63 9 9.38 9.75

0.05

0.1

10:

FIGURE 42.9 The rapid decrease in wetting forces for I Ag when stored incorrectly. While this may seem to be a problem, it is actually an advantage as I Ag is supposed to tarnish as a function of exposure to air. If it does not tarnish, there is too much organic contamination in the deposit which will produce its own series of problems.

OSP With the exception of the first generation of organic coatings, which were mono layers of approx 40 in thickness and were very sensitive to handling/storage, the current generation of OSP coatings are robust and have excellent shelf life. (See Fig. 42.12 Their ultimate failure is a gradual break down of the deposit and subsequent formation of copper oxide. Even as this occurs, the reduction in solderability performance is not as dramatic as with other surface finishes naturally occurring copper oxide not being very tenacious and/or hard to reduce. I Sn This is one of the more difficult surface finishes to correctly apply and maintain from a chemical view point. As such, the possibilities for solderability defects are many. Both the basis metal (copper) and the I Sn deposit have a natural affinity for one another. The copper migrates through the tin as a function of time and temperature; the hotter the temperature the shorter the time to reach the surface. Once there, the intermetallic oxidizes and becomes non-solderable. As a function of plating, copper is displaced from the surface of the PWB and contaminates the plating bath; potentially reducing the mean time for copper to reach the surface of the part. The deposit thickness likewise plays a crucial role in determining shelf life the thinner the deposit, the shorter the shelf life all things being equal. In addition to this, the catalyst used to make the plating chemistry work (Thiourea) can

the encoder tracking can be assigned to one cog, we have a completely different situation. In the eight-processor Propeller system, we can do this with ease. The pseudocode for holding a motor at one position is as follows:

0. 0 37 5 0. 75 1. 12 5 1. 5 1. 87 5 2. 25 2. 62 5 6. 6 37 5 6. 7 7. 5 12 5 7. 5 7. 87 5 8. 25 8. 62 5 3. 3 37 5 3. 75 4. 12 5 4. 5 4. 87 5 5. 25 5. 62 5 9. 9 37 5 9. 75

FIGURE 42.10 A gradual reduction in wetting forces over 629 days of correct storage for Immerssion Silver (I Ag) is shown.